Periodic Activity of Metals

Periodic Trends and the Properties of the Elements

Introduction

Elements are classified based on similarities, differences, and trends in their properties, including their chemical reactions.

The reactions of alkali and alkaline earth metals with water are pretty spectacular chemical reactions. Mixtures bubble and

boil, fizz and hiss, and may even smoke and burn. Introduce the study of the periodic table and periodic trends with this

exciting demonstration of the activity of metals.

Concepts

• Alkali and alkaline earth metals • Periodic table and trends

• Physical and chemical properties • Metal activity

Materials

Calcium turnings, Ca, 0.3 g Beaker, Berzelius (tall-form), Pyrex

, 500-mL, 4

Lithium metal, Li, precut piece Forceps or tongs

Magnesium ribbon, Mg, 3-cm Knife (optional)

Sodium metal, Na, precut piece Petri dishes, disposable, 4

Phenolphthalein, 1% solution, 2 mL Scissors

Water, distilled or deionized, 600 mL

Safety Precautions

Lithium and sodium are flammable, water-reactive, corrosive solids; dangerous when exposed to heat or flame. They react violently

with water to produce flammable hydrogen gas and solutions of corrosive metal hydroxides. Hydrogen gas may be released in sufficient

quantities to cause ignition. Do NOT “scale up” this demonstration using larger pieces of sodium or lithium! These metals are shipped

in dry mineral oil. Store them in mineral oil until immediately before use. Do not allow these metals to stand exposed to air from one

class period to another or for extended periods of time. Purchasing small, pre-cut pieces of lithium and sodium greatly reduces their

potential hazard. Calcium metal is flammable in finely divided form and reacts upon contact with water to give flammable hydrogen

gas and corrosive calcium hydroxide. Magnesium metal is a flammable solid and burns with an intense flame. Perform this

demonstration in a well-ventilated lab only. Do not handle any of the metals with bare hands. Wear chemical splash goggles, chemical-

resistant gloves, and a chemical-resistant apron. All students or spectators should also be wearing chemical splash goggles

during this demonstration. Use a Class D powder fire extinguisher such as dry sand for reactive metals. Please review current

Material Safety Data Sheets for safety, handling, and disposal information.

Preparation

1. Obtain four 500-mL, tall-form beakers and label them Li, Na, Mg, and Ca. Add approximately 150 mL of distilled or

deionized water to each beaker. Label four Petri dishes Li, Na, Mg, and Ca and place them next to the beakers.

2. Cut the magnesium ribbon into 3-cm strips using scissors.

3. The precut lithium and sodium metal pieces should be approximately 0.5 cm × 0.5 cm × 0.5 cm, or 0.2–0.3 g each.

4. Divide the calcium turnings into five samples, about 0.3 g each.

Procedure

1. Place one piece of each metal in its respective Petri dish on an overhead projector. Observe and compare the physical

properties of the metals: Color, luster (shine), hardness, and malleability.

2. Have students record the properties of the elements on the worksheet.

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Periodic Activity of Metals continued

3. Discuss possible “rankings” of the metals with respect to their physical properties. Which metal appears to be the shiniest?

Softest (or hardest)?

4. Use forceps or tongs to quickly transfer one piece of sodium metal to water in its respective labeled (Na) beaker. Have

students make detailed observations of the resulting chemical reaction and record all observations on the worksheet. Sodium

metal, which initially floats on the surface, immediately begins to “hiss and sizzle” on the water surface and appears to melt. Popping

sounds are heard and the metal begins to bounce around and finally disappear. A smoky gas forms and ignites the metal on the surface of

the water. Sparks may be seen where the metal ignites.

5. Repeat step 4 using lithium metal in its respective (Li) beaker. As observations are made, ask students to compare the rate

and intensity of the reaction versus that of sodium. Record all observations on the worksheet.

6. Repeat step 4 twice more, using calcium and magnesium, respectively. Compare the activity of each metal against the

previous metal and against sodium as a reference metal. Record all observations

7. Refer to the observations to rank the metals in order of their reactivity. Which metal is most active? Least active? Answer

Questions #1 and #2 on the worksheet.

8. Refer to Question #3 on the worksheet. Based on class discussion, draw arrows to indicate the directions in which metal

activity increases across a row and within a column in the periodic table, as shown below.

Activity increases

Na Mg

9. Ask students to predict the activity of potassium metal based on the observed periodic trend in the activity of metals

(Answer Question #4 on the worksheet). Discuss the extreme reactivity of potassium metal (and why it was not used in this

demonstration).

10. After the metals have reacted (with the exception of magnesium, which does not react under these conditions), add 5 drops

of phenolphthalein solution to the mixture in each beaker.

11. Observe the color change(s) and discuss what a color change indicates. What types of solutions exhibit this color change?

Discuss the possible identity of the product(s). (See the Discussion section.)

12. Write balanced chemical equations for the reactions of the metals with water (Question #5). Discuss the evidence for the

formation of both hydrogen gas and metal hydroxides.

13. (Optional) Have students write a paragraph describing in words the physical and chemical properties of one of the metals.

Instruct students to include as much descriptive detail as possible. An example is given below.

“Sodium is a soft, silver-white solid. Upon exposure to air it gradually develops a white oxide coating. It can be cut with a

knife. It is less dense than water and reacts spontaneously and vigorously on contact with water. The metal piece appears to

pop or sizzle on the surface and a smoky white gas forms. The metal may ignite on the surface of the water in the vicinity

of the smoke. The products are hydrogen gas and sodium hydroxide. The hydrogen gas that is formed ‘pops’ and briefly

ignites. Sodium hydroxide makes the solution basic (red) to phenolphthalein indicator.”

Disposal

Please consult your current Flinn Scientific Catalog/Reference Manual for general guidelines and specific procedures governing the

disposal of laboratory waste. Use tongs or forceps to remove unreacted magnesium from its beaker. Dispose of excess magnesium

metal according to Flinn Suggested Disposal Method #26a. Do not dispose of any of the other reaction mixtures until all

of the metal in each has completely reacted. The resulting basic solutions in each beaker can be neutralized and disposed of

according to Flinn Suggested Disposal Method #10.

Periodic Activity of Metals continued

Tips

• We strongly recommend the purchase of small quantities only of sodium and lithium metal. Purchase only the

amounts that will be used in one academic year. Sodium and lithium are available in small, precut pieces that are

suitable for demonstrations (Flinn Catalog Nos. S0329 and L0057, respectively).

• We do not recommend the use of potassium in the high school science laboratory. Potassium is considerably more water-

reactive than sodium and is a serious fire and explosion hazard. There is a significant and often undetectable explosion

risk because of the propensity of potassium to form a superoxide (peroxide) coating on its surface. Potassium reacts with

oxygen in air to form a coating of yellow potassium superoxide (KO

), even when the metal is stored under dry mineral

oil. Old pieces of potassium are thus extremely dangerous. When the metal is cut, the pressure of the knife may touch off

a violent, uncontrollable, explosive reaction between the superoxide coating and the underlying metal.

• Calcium metal must be reasonably fresh to react with water. Old (dull) calcium metal will not react with water.

• The reactions of sodium and lithium with water may be quite vigorous—we recommend using tall-form (Berzelius)

beakers to contain any molten metal pieces that may splatter. Do NOT scale up this demonstration.

• The use of a ChemCam

™

video camera will make it easier for students to observe the appearance and properties of the

metal pieces.

• Demonstrate the softness of lithium and sodium by showing how the metal pieces can be cut with a dry spatula or knife.

• In ranking the metals in order of their activity, it is easier to begin with pairwise comparisons. Which is more active—

sodium or lithium? Calcium or magnesium? Magnesium or sodium?

• Is the activity of metals related to their hardness? Density? The answer, a firm “maybe,” depends on the comparisons

being made. The alkali metals as a group are softer and less dense than their nearest alkaline earth metal neighbors, and

also more reactive. Within the group of alkali metals, however, the opposite trend is observed. Lithium is less dense but

also less reactive than sodium.

Discussion

Sodium reacts with water to form hydrogen gas and sodium hydroxide, according to the following balanced chemical equation.

2Na(s) + 2H

O(l) → H

(g) + 2NaOH(aq) + Heat

As sodium metal reacts with water, a great deal of heat is generated. The sodium melts and seems to float or bob on the water

surface. The oxide coating that may have dulled the metal disappears and sodium’s silvery gray, metallic character is more

apparent. The evolution of hydrogen gas is evident in the production of a white smoke, which pops and ignites as it is heated

above its flash point. The formation of sodium hydroxide, a strong base, is inferred from the color change observed with

phenolphthalein, an acid–base indicator. Phenolphthalein is colorless in neutral or slightly basic solutions (pH < 8) and red in

more basic solutions (pH >10). Between pH 8 and 10 phenolphthalein appears various shades of pink.

The balanced chemical equations for reactions of other active metals with water are given below.

2Li(s) + 2H

O(l) → H

(g) + 2LiOH(aq)

Ca(s) + 2H

O(l) → H

(g) + Ca(OH)

(aq)

Of the four metals tested, sodium is the most active and magnesium is the least active. Magnesium does not react with water

under these conditions (it may react slightly in hot water). The order of metal reactivity is Na > Li, Ca >> Mg. Periodic trends

in the activity of metals are generally attributed to differences in their ionization energies. The activity of metals increases as

the value of their first ionization energy decreases. Within a vertical column (group or family) of elements in the periodic table,

ionization energy decreases from top to bottom. As a result, metal activity increases going down a column in the periodic table

(K > Na > Li; Ca > Mg). Across a horizontal row (period or series) in the periodic table, ionization energy also increases from

left to right. As a result, metal activity decreases from left to right across a row in the periodic table (Na >> Mg; K >> Ca).

Periodic Activity of Metals continued

Connecting to the National Standards

This laboratory activity relates to the following National Science Education Standards (1996):

Unifying Concepts and Processes: Grades K–12

Evidence, models, and explanation

Constancy, change, and measurement

Content Standards: Grades 5–8

Content Standard A: Science as Inquiry

Content Standard B: Physical Science, properties and changes of properties in matter, transfer of energy

Content Standards: Grades 9–12

Content Standard A: Science as Inquiry

Content Standard B: Physical Science, structure of atoms, structure and properties of matter, chemical reactions, inter-

actions of energy and matter

Answers to Worksheet Questions

Data Table

Physical Properties of Metals — Observations

Lithium

Dark gray–black solid. The surface has

a slight bluish sheen and a “tacky” tex-

ture, like hard rubber. Can be cut with

a knife.

Magnesium

Silvery gray, shiny, hard metal “ribbon.”

The metal can be easily bent and cut

with scissors. Light weight.

Sodium

Soft, silver–white, shiny metallic solid.

Can be cut with a knife.

Calcium

Shiny, dark silver–gray metal pieces;

hard—not easily cut. Rough texture.

Reactions of Metals with Water — Observations

Lithium

Lithium floats on water—reacts slowly

at first, then more vigorously. “Sizzles”

and bounces on water. Bubbles of gas,

smoky fumes observed as metal turns

white around edges and then “disap-

pears” after about 5 minutes.

Magnesium

Magnesium does not react with water at

room temperature.

Sodium

Sodium floats on the water—immedi-

ately begins to “sizzle” and hiss. Bubbles

of gas, heat released. Sodium melts

and “bounces” around. Sparks as gas or

metal ignites. The reaction is very fast—

metal disappears within 30 seconds.

Final solution is slightly cloudy.

Calcium

Metal sinks, then mixture slowly begins

to bubble, sizzle and fume. Metal turns

white and melts and water becomes

very cloudy.

Periodic Activity of Metals continued

Questions

1. What is the common name for the family of metals in (a) Group 1 and (b) Group 2 of the periodic table?

(a) Alkali metals (b) Alkaline earth metals

2. Rank the four metals used in this demonstration from most active to least active based on their reactivity with water.

Na > Li > Ca >> Mg

3. The metals are arranged below according to their relative positions in the periodic table. (a) Draw a horizontal arrow across

the top to show the direction in which the activity of a metal increases across a period (row) in the periodic table. (b) Draw

a vertical arrow along the side to show the direction in which the activity of a metal increases within a group (family) in the

periodic table.

Group 1 Group 2

Period 2 Li Metal activity increases in the directions the arrows point.

Period 3 Na Mg

Period 4 K Ca

4. Look up the position of potassium metal in the periodic table and write in the symbol for potassium in the appropriate

location in the arrangement of metals in Question #3. Based on the trend in metal activity observed in this activity, predict

whether potassium metal is more or less reactive than sodium with water.

Potassium metal is dangerously reactive with water (and air). It is more reactive than both sodium and calcium. Metal activity increases

going down a column in the periodic table.

5. Write a balanced chemical equation for the reaction of (a) sodium metal and (b) calcium metal with water.

a. 2Na(s) + 2H

O(l) → 2NaOH(aq) + H

(g)

b. Ca(s) + 2H

O(l) → Ca(OH)

(aq) + H

(g)

Reference

This activity was adapted from a demonstration in The Periodic Table, Volume 4 in the Flinn ChemTopic

™

Labs series, Cesa, I.,

Editor; Flinn Scientific: Batavia, IL (2002).

Flinn Scientific—Teaching Chemistry

™

eLearning Video Series

A video of the Periodic Activity of Metals activity, presented by Irene Cesa, is available in Periodic Trends and the Properties of the

Elements, part of the Flinn Scientific—Teaching Chemistry eLearning Video Series.

Materials for Periodic Activity of Metals are available from Flinn Scientific, Inc.

Materials required to perform this activity are available in the Periodic Activity of Metals—Chemical Demonstration Kit available

from Flinn Scientific. Materials may also be purchased separately.

Catalog No. Description

AP7180 Periodic Activity of Metals—Chemical Demonstration

Kit

GP1060 Beaker, Berzelius, 500-mL

C0345 Calcium 10 g

L0024 Lithium, 10 g

M0139 Magnesium Ribbon, 12.5 g

S0329 Sodium, 5 pieces

Consult your Flinn Scientific Catalog/Reference Manual for current prices.

Periodic Activity of Metals continued

Periodic Activity of Metals Worksheet

Data Table

Physical Properties of Metals — Observations

Lithium Magnesium

Sodium Calcium

Reactions of Metals with Water — Observations

Lithium Magnesium

Sodium Calcium

Questions

1. What is the common name for the family of metals in (a) Group 1 and (b) Group 2 of the periodic table?

2. Rank the four metals used in this demonstration from most active to least active based on their reactivity with water.

3. The metals are arranged below according to their relative positions in the periodic table. (a) Draw a horizontal arrow

across the top to show the direction in which the activity of a metal increases across a period (row) in the periodic table. (b)

Draw a vertical arrow along the side to show the direction in which the activity of a metal increases within a group (family)

in the periodic table.

Group 1 Group 2

Period 2 Li

Period 3 Na Mg

Period 4 Ca

4. Look up the position of potassium metal in the periodic table and write in the symbol for potassium in the appropriate

location in the arrangement of metals in Question #3. Based on the trend in metal activity observed in this activity, predict

whether potassium metal is more or less reactive than sodium with water.

5. Write a balanced chemical equation for the reaction of (a) sodium metal and (b) calcium metal with water.